I'll be interested in the .stl files as I have a 3D printer.
Would a female version of the mould not be more useful, as that is what you are trying to copy?
I've read that CNC machines can be used to accurately copy the shape of the mould, but I've never seen it done. I suspect that it would only be high level engine builders (such as F1) that would do it.
When I used to do it on Mini engines we knew where the oil and water ports were and knew what parts of the head to attack and wheat parts to leave alone. We knew this because the heads were freely available and could be sliced to have a good look inside.
I'd recommend you can get hold of a 2nd hand head and cut it up to take a good look inside. It will show you the oil and water galleries as well as the OEM throat shapes. You will be able to see and mark out the areas that can be removed.
I didn't have access to a flowbench when I was doing it and just did what I thought was right. If I were to do it again, I'd use a flow bench to check that the cylinder head flow was balanced. I think that balancing the flow is more beneficial than just having more flow through each valve.
There are some very good books on the subject and I've spent a lot of time reading them.
Good luck, have fun and enjoy the results...
Here's a link to my
Youtube videos. None of them are specifically about porting, but you can see that there is not much that I've not had a go at.